Zircon is the main mineral in the majority of igneous and metamorphic rocks with Zr as an essential structural constituent. It is a host for significant fractions of the whole-rock abundance of U, Th, Hf, and the REE (Sawka 1988, Bea 1996, O’Hara et al. 2001). These elements are important geochemically as process indicators or parent isotopes for age determination. The importance of zircon in crustal evolution studies is underscored by its predominant use in U-Th-Pb geochronology and investigations of the temporal evolution of both the crust and lithospheric mantle. In the past decade an increasing interest in the composition of zircon, trace-elements in particular, has been motivated by the effort to better constrain in situ microprobe-acquired isotopic ages. Electron-beam compositional imaging and isotope-ratio measurement by in situ beam techniques—and the micrometer-scale spatial resolution that is possible—has revealed in many cases that single zircon crystals contain a record of multiple geologic events. Such events can either be zircon-consuming, alteration, or zircon-forming and may be separated in time by millions or billions of years. In many cases, calculated zircon isotopic ages do not coincide with ages of geologic events determined from other minerals or from whole-rock analysis. To interpret the geologic validity and significance of multiple ages, and ages unsupported by independent analysis of other isotopic systems, has been the impetus for most past investigations of zircon composition. Some recent compositional investigations of zircon have not been directly related to geochronology, but to the ability of zircon to influence or record petrogenetic processes in igneous and metamorphic systems.

Sedimentary rocks may also contain a significant fraction of zircon. Although authigenic zircon has been reported (Saxena 1966, Baruah et al. 1995, Hower et al. 1999), it appears to be very rare and may in fact be related to …

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The Composition of Zircon and Igneous and Metamorphic Petrogenesis

We present and interpret Global Positioning System (GPS) measurements of crustal motions for the period 1988–1997 at 189 sites extending east-west from the Caucasus mountains to the Adriatic Sea and north-south from the southern edge of the Eurasian plate to the northern edge of the African plate. Sites on the northern Arabian platform move 18±2 mm/yr at N25°±5°W relative to Eurasia, less than the NUVEL-1A circuit closure rate (25±1 mm/yr at N21°±7°W). Preliminary motion estimates (1994–1997) for stations located in Egypt on the northeastern part of Africa show northward motion at 5–6±2 mm/yr, also slower than NUVEL-IA estimates (10±1 mm/yr at N2°±4°E). Eastern Turkey is characterized by distributed deformation, while central Turkey is characterized by coherent plate motion (internal deformation of <2 mm/yr) involving westward displacement and counterclockwise rotation of the Anatolian plate. The Anatolian plate is de-coupled from Eurasia along the right-lateral, strike-slip North Anatolian fault (NAF). We derive a best fitting Euler vector for Anatolia-Eurasia motion of 30.7°± 0.8°N, 32.6°± 0.4°E, 1.2°±0.1°/Myr. The Euler vector gives an upper bound for NAF slip rate of 24±1 mm/yr. We determine a preliminary GPS Arabia-Anatolia Euler vector of 32.9°±1.2°N, 40.3°±1.1°E, 0.8°±0.2°/Myr and an upper bound on left-lateral slip on the East Anatolian fault (EAF) of 9±1 mm/yr. The central and southern Aegean is characterized by coherent motion (internal deformation of <2 mm/yr) toward the SW at 30±1 mm/yr relative to Eurasia. Stations in the SE Aegean deviate significantly from the overall motion of the southern Aegean, showing increasing velocities toward the trench and reaching 10±1 mm/yr relative to the southern Aegean as a whole.

https://agupubs.onlinelibrary.wiley.com/doi/pdf/10.1029/1999JB900351

Global Positioning System constraints on plate kinematics and dynamics in the eastern Mediterranean and Caucasus

Convective removal of lower lithosphere beneath the Tibetan Plateau can account for a rapid increase in the mean elevation of the Tibetan Plateau of 1000 m or more in a few million years. Such uplift seems to be required by abrupt tectonic and environmental changes in Asia and the Indian Ocean in late Cenozoic time. The composition of basaltic volcanism in northern Tibet, which apparently began at about 13 Ma, implies melting of lithosphere, not asthenosphere. The most plausible mechanism for rapid heat transfer to the midlithosphere is by convective removal of deeper lithosphere and its replacement by hotter asthenosphere. The initiation of normal faulting in Tibet at about 8 (± 3) Ma suggests that the plateau underwent an appreciable increase in elevation at that time. An increase due solely to the isostatic response to crustal thickening caused by India's penetration into Eurasia should have been slow and could not have triggered normal faulting. Another process, such as removal of relatively cold, dense lower lithosphere, must have caused a supplemental uplift of the surface. Folding and faulting of the Indo-Australian plate south of India, the most prominent oceanic intraplate deformation on Earth, began between about 7.5 and 8 Ma and indicates an increased north-south compressional stress within the Indo-Australian plate. A Tibetan uplift of only 1000 m, if the result of removal of lower lithosphere, should have increased the compressional stress that the plateau applies to India and that resists India's northward movement, from an amount too small to fold oceanic lithosphere, to one sufficient to do so. The climate of the equatorial Indian Ocean and southern Asia changed at about 6–9 Ma: monsoonal winds apparently strengthened, northern Pakistan became more arid, but weathering of rock in the eastern Himalaya apparently increased. Because of its high altitude and lateral extent, the Tibetan Plateau provides a heat source at midlatitudes that should oppose classical (symmetric) Hadley circulation between the equator and temperate latitudes and that should help to drive an essentially opposite circulation characteristic of summer monsoons. For the simple case of axisymmetric heating (no dependence on longitude) of an atmosphere without dissipation, theoretical analyses by Hou, Lindzen, and Plumb show that an axisymmetric heat source displaced from the equator can drive a much stronger meridianal (monsoonlike) circulation than such a source centered on the equator, but only if heating exceeds a threshold whose level increases with the latitude of the heat source. Because heating of the atmosphere over Tibet should increase monotonically with elevation of the plateau, a modest uplift (1000–2500 m) of Tibet, already of substantial extent and height, might have been sufficient to exceed a threshold necessary for a strong monsoon. The virtual simultaneity of these phenomena suggests that uplift was rapid: approximately 1000 m to 2500 m in a few million years. Moreover, nearly simultaneously with the late Miocene strengthening of the monsoon, the calcite compensation depth in the oceans dropped, plants using the relatively efficient C4 pathway for photosynthesis evolved rapidly, and atmospheric CO2 seems to have decreased, suggesting causal relationships and positive feedbacks among these phenomena. Both a supplemental uplift of the Himalaya, the southern edge of Tibet, and a strengthened monsoon may have accelerated erosion and weathering of silicate rock in the Himalaya that, in turn, enhanced extraction of CO2 from the atmosphere. Thus these correlations offer some support for links between plateau uplift, a downdrawing of CO2 from the atmosphere, and global climate change, as proposed by Raymo, Ruddiman, and Froehlich. Mantle dynamics beneath mountain belts not only may profoundly affect tectonic processes near and far from the belts, but might also play an important role in altering regional and global climates.

Mantle dynamics, uplift of the Tibetan Plateau, and the Indian Monsoon

Statistics and Data Analysis in Geology

Seismic tomography models of the three-dimensional upper mantle velocity structure of the Mediterranean-Carpathian region provide a better understanding of the lithospheric processes governing its geodynamical evolution. Slab detachment, in particular lateral migration of this process along the plate boundary, is a key element in the lithospheric dynamics of the region during the last 20 to 30 million years. It strongly affects arc and trench migration, and causes along-strike variations in vertical motions, stress fields, and magmatism. In a terminal-stage subduction zone, involving collision and suturing, slab detachment is the natural last stage in the gravitational settling of subducted lithosphere.

http://www.mantleplumes.org/WebDocuments/Wortel2000.pdf

Subduction and Slab Detachment in the Mediterranean-Carpathian Region

Subduction-accretion complexes can be approximated as wedge-shaped continua with a rigid buttress behind and a subducting litho-spheric slab beneath. Thick wedges undergoing prograde metamorphism have a negligible long-term yield strength and are likely to exhibit a complex nonlinear viscous rheology. Such a wedge will tend to deform internally until it reaches a stable configuration, in which the gravitational forces generated by the wedge geometry balance the traction exerted on its underside by the subducting slab. Accretion of material at the wedge front will lengthen the wedge and cause it to shorten internally to regain the stable geometry. This shortening will be expressed as late (out-of-sequence) thrusting, backthrusting, and folding. Conversely, underplating of sediment or crustal slices will thicken the wedge, which may need to extend internally to regain stability. Extension will cause listric normal faults that may merge downward into zones of ductile extension. Continued underplating at depth and compensating extension above provides a mechanism for bringing high-P/low-T metamorphic rocks to upper levels in the rear of the wedge, where they are commonly observed. Many major tectonic boundaries in convergent orogens (such as the Coast Range thrust in the Franciscan Complex, major nappe contacts in the Alps, and the contact between the Nevado-Filabride and Higher Betic nappe complexes in the Betic Cordillera) show abrupt increases in metamorphic grade downward across them. This is consistent with their origin or reactivation as uplift-related, extensional structures.

Dynamics of orogenic wedges and the uplift of high-pressure metamorphic rocks

Several features of the Alboran Sea suggest that it may have been a high collisional ridge in Paleogene time that subsequently underwent extensional-collapse, driving radial thrusting around the Gibraltar arc. (1) The basin is underlain by thin (13-20 km) continental crust, has an east-west-trending horst and graben morphology, was the locus of Neogene volcanism, and has subsided 2-4 km since the middle Miocene. (2) Extension and subsidence in the basin coincided in time with outwardly directed thrusting in the surrounding mountain chains. (3) Africa and Europe were converging slowly during this period, so extension must have been driven by internally generated forces. (4) Onshore, rocks metamorphosed at 40 km depth are exposed beneath major low-angle normal faults that separate them from low-grade rocks above. (5) Emplacement of solid bodies of Iherzolite at asthenospheric temperature into the base of the collisional edifice in late Oligocene time suggests detachment of the lithospheric root beneath the collision zone. This would have increased the surface elevation and the potential energy of the system and would have favored extensional collapse of the ridge.

Extensional collapse of thickened continental lithosphere: A working hypothesis for the Alboran Sea and Gibraltar arc

https://dspace.library.uu.nl/bitstream/handle/1874/24823/platt_80_Extensional%20structures.pdf;sequence=1

Extensional structures in anisotropic rocks

The exhumation of high-pressure metamorphic rocks requires either the removal of the overburden that caused the high pressures, or the transport of the metamorphic rocks through the overburden Exhumation cannot be achieved simply by thrusting or strike-slip faulting It may be caused by erosion of shortened and thickened crust, but this is unlikely to be the only mechanism for exhuming rocks from depths greater than about 20 km One or more of the following additional mechanisms may be involved

1 Corner flow of low-viscosity material trapped between the upper and lower plates in a subduction zone can cause upward flow of deeply buried rock, and may explain some occurrences of high-pressure tectonic blocks in melange This process does not, however, appear to be adequate to explain the exhumation of regional high-pressure terrains

2 Buoyancy forces acting directly on metamorphic rock bodies may cause them to rise relative to more dense surroundings This is likely to be the most important mechanism of exhumation of crustal rocks subducted into the mantle, but cannot explain the emplacement of coherent tracts of high-density metamorphic rock into shallow crustal levels Some high-pressure blocks emplaced at shallow levels in accretionary terrains may have been entrained in diapiric intrusions of low-density mud or serpentinite

3 Extension driven by the forces associated with contrasts in surface elevation may explain the exhumation and structural setting of many high-pressure terrains Extension may occur in the upper part of an accretionary wedge thickened by underplating; or it may affect the whole lithosphere in a region of intracontinental convergence, if surface elevation has been increased by the removal of a lithospheric root In the second case extension may be accompanied by magmatism and an evolution towards higher temperature during decompression of the metamorphic terrain

Exhumation of high-pressure rocks: a review of concepts and processes

We integrate petrography and SIMS REE analyses of garnet and polyphase zircon from a pelitic granulite adjacent to the Ronda peridotite, Betic Cordillera, southern Spain to constrain the significance of zircon U–Pb geochronology. Sillimanite inclusions in garnet rims suggest that they grew during decompression, and Ca enrichment in their rims records initiation of partial melting. Chondrite-normalised REE profiles of zircon cores are typically magmatic (positive La to Lu slope and Ce anomaly), whereas overgrowths have flat or negatively sloping heavy-REE profiles (Gd–Lu). The presence of rimmed zircon grains only in the garnet rims and the matrix suggests that this zircon phase grew after garnet had already sequestered heavy REEs, a process documented here by progressive depletion of heavy REE in the garnets from centre to rim. Combined with the textural evidence, we suggest that the U–Pb age of 21.3±0.3 Ma obtained from the zircon rims dates a point on this decompression path rather than the peak metamorphic pressure.

John P. Platt

Papers

Dynamics of orogenic wedges and the uplift of high-pressure metamorphic rocks

Extensional collapse of thickened continental lithosphere: A working hypothesis for the Alboran Sea and Gibraltar arc

Extensional structures in anisotropic rocks

Exhumation of high-pressure rocks: a review of concepts and processes

Dating high-grade metamorphism—constraints from rare-earth elements in zircon and garnet