Institution
Dow Chemical Company
Company•Mumbai, India•
About: Dow Chemical Company is a company organization based out in Mumbai, India. It is known for research contribution in the topics: Polymer & Catalysis. The organization has 17250 authors who have published 23852 publications receiving 450207 citations. The organization is also known as: Dow & Dow Chemical.
Topics: Polymer, Catalysis, Alkyl, Polymerization, Copolymer
Papers published on a yearly basis
Papers
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TL;DR: A water-soluble (at pH 8) aromatic disulfide [5,5′-dithiobis(2-nitrobenzoic acid] has been synthesized and shown to be useful for determination of sulfhydryl groups.
23,232 citations
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TL;DR: Starburst polymers as mentioned in this paper are a class of topological macromolecules which are derived from classical monomers/oligomers by their extraordinary symmetry, high branching and maximized terminal functionality density.
Abstract: This paper describes the first synthesis of a new class of topological macromolecules which we refer to as “starburst polymers.” The fundamental building blocks to this new polymer class are referred to as “dendrimers.” These dendrimers differ from classical monomers/oligomers by their extraordinary symmetry, high branching and maximized (telechelic) terminal functionality density. The dendrimers possess “reactive end groups” which allow (a) controlled moelcular weight building (monodispersity), (b) controlled branching (topology), and (c) versatility in design and modification of the terminal end groups. Dendrimer synthesis is accomplished by a variety of strategies involving “time sequenced propagation” techniques. The resulting dendrimers grow in a geometrically progressive fashion as shown: Chemically bridging these dendrimers leads to the new class of macromolecules—”starburst polymers” (e.g., (A)n, (B)n, or (C)n).
3,372 citations
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TL;DR: It is shown that the use of substrate surface energy patterning to direct the flow of water-based conducting polymer inkjet droplets enables high-resolution definition of practical channel lengths of 5 micrometers, and high mobilities were achieved.
Abstract: Direct printing of functional electronic materials may provide a new route to low-cost fabrication of integrated circuits. However, to be useful it must allow continuous manufacturing of all circuit components by successive solution deposition and printing steps in the same environment. We demonstrate direct inkjet printing of complete transistor circuits, including via-hole interconnections based on solution-processed polymer conductors, insulators, and self-organizing semiconductors. We show that the use of substrate surface energy patterning to direct the flow of water-based conducting polymer inkjet droplets enables high-resolution definition of practical channel lengths of 5 micrometers. High mobilities of 0.02 square centimeters per volt second and on-off current switching ratios of 10 5 were achieved.
3,190 citations
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TL;DR: Starburst dendrimers are three-dimensional, highly ordered oligomeric and polymeric compounds formed by reiterative reaction sequences starting from smaller molecules—“initiator cores” such as ammonia or pentaerythritol.
Abstract: Starburst dendrimers are three-dimensional, highly ordered oligomeric and polymeric compounds formed by reiterative reaction sequences starting from smaller molecules—“initiator cores” such as ammonia or pentaerythritol. Protecting group strategies are crucial in these syntheses, which proceed via discrete “Aufbau” stages referred to as generations. Critical molecular design parameters (CMDPs) such as size, shape, and surface chemistry may be controlled by the reactions and synthetic building blocks used. Starburst dendrimers can mimic certain properties of micelles and liposomes and even those of biomolecules and the still more complicated, but highly organized, building blocks of biological systems. Numerous applications of these compounds are conceivable, particularly in mimicking the functions of large biomolecules as drug carriers and immunogens. This new branch of “supramolecular chemistry” should spark new developments in both organic and macromolecular chemistry.
3,022 citations
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TL;DR: Bisphenol A (CAS 85-05-7) is "slightly to moderately" toxic and has low potential for bioaccumulation in aquatic organisms, with most levels nondetected.
1,601 citations
Authors
Showing all 17257 results
Name | H-index | Papers | Citations |
---|---|---|---|
Richard H. Friend | 169 | 1182 | 140032 |
Tobin J. Marks | 159 | 1621 | 111604 |
James J. Collins | 151 | 669 | 89476 |
Craig J. Hawker | 134 | 741 | 72032 |
Mark A. Ratner | 127 | 968 | 68132 |
Keith A. Johnson | 120 | 798 | 51034 |
Jeffrey Schlom | 111 | 713 | 45440 |
Marc A. Hillmyer | 103 | 574 | 36643 |
Charles R. Martin | 102 | 358 | 41696 |
Bert M. Weckhuysen | 100 | 767 | 40945 |
Amy S. Lee | 100 | 487 | 35019 |
Keith P. Johnston | 95 | 524 | 32307 |
Michael D. Ward | 95 | 823 | 36892 |
Fred W. McLafferty | 92 | 457 | 35795 |
Benny D. Freeman | 92 | 463 | 37928 |