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A review of research on spontaneous combustion of coal

TLDR
In this article, the authors focused on the global position of the study carried out by academics, research institutes and industries on spontaneous combustion of coal and coal mine fires and evaluated the generally used spontaneous combustion techniques to predict the spontaneous combustion liability of coal.
Abstract
Coal oxidation at low temperatures is the heat source liable for the self-heating and spontaneous combustion of coal. This phenomenon has imposed severe problems in coal related industries. Attempts to understand this phenomenon by previous researchers have provided significant progress. It is well-known that coal oxidation at low temperatures involves oxygen consumption and formation of gaseous and solid oxidation products. This process is majorly influenced by temperature, oxidation history of coal, coal properties, particle size distribution of the coal, etc. The current understanding of the phenomenon of self-heating and spontaneous combustion of coal is discussed along with the different experimental and numerical models established to predict self-heating characteristics of coal. This paper focuses on the global position of the study carried out by academics, research institutes and industries on spontaneous combustion of coal and coal mine fires. Within this framework, the generally used spontaneous combustion techniques to predict the spontaneous combustion liability of coal were evaluated. These techniques are well-known in their usage, but no specific method has become a standard to predict the spontaneous combustion liability. Further study is still needed to indicate a number of impending issues and to obtain a more complete understanding on the phenomenon.

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Citations
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Journal ArticleDOI

Reaction pathways and cyclic chain model of free radicals during coal spontaneous combustion

TL;DR: In this article, the authors established reaction pathways of free radicals during coal spontaneous combustion based on typical active free radicals by quantum chemistry method and calculated the specific structural parameters and thermodynamic data for reactions (R1~R9) are calculated to reveal the reaction process.
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Heat effects and kinetics of coal spontaneous combustion at various oxygen contents

TL;DR: In this paper, the effect of oxygen concentration on the exothermic characteristics of coal spontaneous combustion (CSC) was explored with the aid of synchronous thermal analyzer, and the Gaussian function was adopted to perform the multimodal fitting for the oxidation ex-othermic stage of CSC.
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Microstructure of coal spontaneous combustion in low-oxygen atmospheres at characteristic temperatures

TL;DR: In this paper, the authors investigated the evolution of coal microstructure during spontaneous combustion in an oxygen-lean atmosphere, and the sensitivity of different active functional groups to oxygen concentrations was analyzed.
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Influence of antioxidants on spontaneous combustion and coal properties

TL;DR: In this article, the influence of antioxidants on coal properties and SPONCOM liability of coal samples collected from South African coal mines was investigated, and gypsum, which has been used for the first time, proves to be an economically viable option compared to other antioxidants on both laboratory and medium scale tests.
Journal ArticleDOI

Microstructure of coal spontaneous combustion in low-oxygen atmospheres at characteristic temperatures

TL;DR: In this paper , the authors investigated the evolution of coal microstructure during spontaneous combustion in an oxygen-lean atmosphere, and the sensitivity of different active functional groups to oxygen concentrations was analyzed.
References
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Journal ArticleDOI

Numerical study on effects of coal properties on spontaneous heating in longwall gob areas

TL;DR: In this paper, a computational fluid dynamics (CFD) study was conducted to model effects of coal properties on the potential for spontaneous heating in longwall gob (mined-out) areas.
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A study of spontaneous combustion characteristics of a turkish lignite: particle size, moisture of coal, humidity of air

TL;DR: In this paper, the authors evaluated the spontaneous combustion characteristics of Askale lignite from Turkey using Crossing Point Methods adapted to our laboratories conditions, and determined the three predominant oxygen functional groups (carboxyl, hydroxyl and carbonyl) in untreated and moist coal samples with wet chemical methods.
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Low-temperature oxidation of coal. 3. Modelling spontaneous combustion in coal stockpiles

TL;DR: In this paper, a reaction-diffusion model for low-temperature oxidation of coal was developed and used to extract kinetic rate parameters for a Wyoming subbituminous coal.
Journal ArticleDOI

Alcohols as H-donor media in coal conversion. 1. Base-promoted H-donation to coal by isopropyl alcohol☆

TL;DR: In this article, coal was converted by methanol/KOH systems to a product which was extractable by pyridine fully, and 15-25% of the mixture was enriched in hydrogen relative to the starting coal.
Journal Article

Relations between Coal Properties and Spontaneous Combustion Parameters

TL;DR: The results of linear and multiple regression analyses to determine the relationship between spontaneous combustion parameters (derived from time-temperature curves obtained from laboratory tests) and coal parameters (obtained from proximate, ultimate and petrographic analyses) have been explained as mentioned in this paper.
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