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Journal ArticleDOI

Thermal desorption of gases

P.A. Redhead
- 01 Jul 1962 - 
- Vol. 12, Iss: 4, pp 203-211
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TLDR
In this paper, the activation energy, rate constant and order of reaction from flash-filament desorption experiments were examined, and two heating schedules were considered: a linear variation of sample temperature with time (T = T 0+st), and a reciprocal temperature variation (1 T = 1 T 0 −αt).
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This article is published in Vacuum.The article was published on 1962-07-01. It has received 3192 citations till now. The article focuses on the topics: Thermal desorption & Thermal desorption spectroscopy.

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Citations
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Structure and growth of self-assembling monolayers

TL;DR: In this article, the structural phases and the growth of self-assembled monolayers (SAMs) are reviewed from a surface science perspective, with emphasis on simple model systems, and a summary of the techniques used for the study of SAMs is given.
Journal ArticleDOI

Growth and applications of Group III-nitrides

TL;DR: In this article, the chemical and thermal stability of epitaxial nitride films is discussed in relation to the problems of deposition processes and the advantages for applications in high-power and high-temperature devices.
Journal ArticleDOI

Chemisorption of CO on the Pt(111) surface

TL;DR: The work function at first decreases, exhibits a (temperature-dependent) minimum at θ = 13, attains nearly the value of the clean surface at 12 and again exhibits a second (shallow) minimum around 0.68 as mentioned in this paper.
Journal ArticleDOI

Thermal desorption from metal surfaces: A review

TL;DR: In this paper, an attempt is made to draw correlations between thermal desorption and structural studies of chemisorption on metal surfaces, in particular with relation to the adsorption of hydrogen and carbon monoxide on tungsten.
Journal ArticleDOI

Adsorption of hydrogen on nickel single crystal surfaces

TL;DR: In this paper, the effect of hydrogen adsorption on Ni(111, (100), and (110) surfaces was studied by means of LEED; energy loss spectroscopy, flash desorption, and work function measurements.
References
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Journal ArticleDOI

Kinetic and Experimental Basis of Flash Desorption

TL;DR: In this article, the authors derived both qualitative and quantitative information on the kinetics of gas desorption from measurements at continuously changing temperature using the Bayard-Alpert gauge.
Journal ArticleDOI

Structure-sensitive chemisorption: The mechanism of desorption from tungsten

TL;DR: The validity of measurements on evaporated tungsten films has been examined and found in doubt; the flash-filament technique has therefore been extended to yield data on the stability of binding states of gases adsorbed on metals.
Journal ArticleDOI

Low‐Temperature Chemisorption. I. Flash Desorption of Nitrogen

TL;DR: In this paper, the authors applied flash desorption to a study of the low-temperature interactions of N2 with an initially clean tungsten surface and found that molecular nitrogen dissociate into atoms on adsorption even at 115°K, at a rate which diminishes with increasing temperature, but is initially independent of surface concentration.
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