The long-standing popularity of thermoelectric materials has contributed to the creation of various thermoelectric devices and stimulated the development of strategies to improve their thermoelectric performance. In this review, we aim to comprehensively summarize the state-of-the-art strategies for the realization of high-performance thermoelectric materials and devices by establishing the links between synthesis, structural characteristics, properties, underlying chemistry and physics, including structural design (point defects, dislocations, interfaces, inclusions, and pores), multidimensional design (quantum dots/wires, nanoparticles, nanowires, nano- or microbelts, few-layered nanosheets, nano- or microplates, thin films, single crystals, and polycrystalline bulks), and advanced device design (thermoelectric modules, miniature generators and coolers, and flexible thermoelectric generators). The outline of each strategy starts with a concise presentation of their fundamentals and carefully selected examples. In the end, we point out the controversies, challenges, and outlooks toward the future development of thermoelectric materials and devices. Overall, this review will serve to help materials scientists, chemists, and physicists, particularly students and young researchers, in selecting suitable strategies for the improvement of thermoelectrics and potentially other relevant energy conversion technologies.

Advanced Thermoelectric Design: From Materials and Structures to Devices

Buckling is exploited to design a new class of three-dimensional metamaterials with negative Poisson's ratio. A library of auxetic building blocks is identified and procedures are defined to guide their selection and assembly. The auxetic properties of these materials are demonstrated both through experiments and finite element simulations and exhibit excellent qualitative and quantitative agreement.

3D Soft Metamaterials with Negative Poisson's Ratio

Materials and structures with negative Poisson's ratio exhibit a counter-intuitive behaviour. Under uniaxial compression (tension), these materials and structures contract (expand) transversely. The materials and structures that possess this feature are also termed as 'auxetics'. Many desirable properties resulting from this uncommon behaviour are reported. These superior properties offer auxetics broad potential applications in the fields of smart filters, sensors, medical devices and protective equipment. However, there are still challenging problems which impede a wider application of auxetic materials. This review paper mainly focuses on the relationships among structures, materials, properties and applications of auxetic metamaterials and structures. The previous works of auxetics are extensively reviewed, including different auxetic cellular models, naturally observed auxetic behaviour, different desirable properties of auxetics, and potential applications. In particular, metallic auxetic materials and a methodology for generating 3D metallic auxetic materials are reviewed in details. Although most of the literature mentions that auxetic materials possess superior properties, very few types of auxetic materials have been fabricated and implemented for practical applications. Here, the challenges and future work on the topic of auxetics are also presented to inspire prospective research work. This review article covers the most recent progress of auxetic metamaterials and auxetic structures. More importantly, several drawbacks of auxetics are also presented to caution researchers in the future study.

Auxetic metamaterials and structures: a review

Recent advances in three dimensional (3D) printing technology that allow multiple materials to be printed within each layer enable the creation of materials and components with precisely controlled heterogeneous microstructures. In addition, active materials, such as shape memory polymers, can be printed to create an active microstructure within a solid. These active materials can subsequently be activated in a controlled manner to change the shape or configuration of the solid in response to an environmental stimulus. This has been termed 4D printing, with the 4th dimension being the time-dependent shape change after the printing. In this paper, we advance the 4D printing concept to the design and fabrication of active origami, where a flat sheet automatically folds into a complicated 3D component. Here we print active composites with shape memory polymer fibers precisely printed in an elastomeric matrix and use them as intelligent active hinges to enable origami folding patterns. We develop a theoretical model to provide guidance in selecting design parameters such as fiber dimensions, hinge length, and programming strains and temperature. Using the model, we design and fabricate several active origami components that assemble from flat polymer sheets, including a box, a pyramid, and two origami airplanes. In addition, we directly print a 3D box with active composite hinges and program it to assume a temporary flat shape that subsequently recovers to the 3D box shape on demand.

https://iopscience.iop.org/article/10.1088/0964-1726/23/9/094007/pdf

Active origami by 4D printing

A comprehensive review of techniques for natural fibers as reinforcement in composites: Preparation, processing and characterization.

Auxetic polymeric materials are a special kind of materials that exhibit negative Poisson’s ratio (NPR) effect. They get fatter when stretched and thinner when compressed. Auxetic behavior is a scale-independent property which can be achieved at different structural levels from molecular to macroscopic levels. The internal structure of material plays an important role in obtaining auxetic effect. Because of NPR effect, auxetic polymeric materials demonstrate a series of particular characteristics when compared with conventional materials. In recent years, a variety of auxetic polymeric materials have been designed and fabricated for diverse applications. This article presents a review on advances in this area. The emphasis is focused on the geometrical structures and models, particular properties and applications of auxetic polymeric materials developed.

	 

	Key words: Auxetic, negative passion’s ratio, modeling, structure, polymer.

A review on auxetic structures and polymeric materials

Bamboo fibers are a new kind of natural materials which have a big potential application in textile field due to some of their particular properties. However, high crystallinity and orientation structure can result in some undesirable properties and this will limit their further applications as textile materials. As a common used way, mercerization was adapted to treat bamboo fibers in this work in order to improve their undesirable properties. X-ray diffraction (XRD) was used to characterize their microstructure after treatment with NaOH. The amount of cellulose II and the crystallinity index based on the XRD results were calculated for the evaluation of the effectiveness of the different treatment conditions, such as alkali concentration, mercerization duration and temperature, as well as tension applied to the fibers during mercerization, on the transformation degree of cellulose I to cellulose II and decrystallization of the mercerized bamboo fibers. It has been found that each condition has different effects and that the greatest effectiveness of crystal lattice conversion and decrystallization could be achieved with such mercerization condition: 16 % alkali concentration, 10 minutes of mercerization at 20 °C without tension applied to the fibers.

X-ray diffraction study of bamboo fibers treated with NaOH

This paper presents a study of using weft-knitting technology to fabricate negative Poisson’s ratio (NPR) knitted fabrics, which exhibit the unusual property of becoming wider when stretched. Based on a geometrical analysis of a three-dimensional NPR structure constructed with parallelogram planes of the same shape and size, a new kind of NPR weft-knitted fabric was firstly designed and fabricated on a computerized flat-knitting machine. Then the NPR values of these fabrics were evaluated and compared with those from the theoretical calculations. The results show that all knitted fabrics have the NPR effect, which decreases with increased strain in the course direction. This variation trend is consistent with the theoretical prediction. The results also show that the main structure parameter affecting the NPR effect of a fabric is the opening angle at its initial state. Fabric with a smaller opening angle will have higher NPR values. This paper demonstrates the feasibility of fabricating NPR-knitted fabri...

Negative Poisson’s Ratio Weft-knitted Fabrics:

Cushioning materials generally absorb kinetic mechanical energy under compression actions at a relatively constant stress over a large range of displacement. However, cushioning materials widely us...

Compression behavior of warp-knitted spacer fabrics for cushioning applications

This paper presents a study of the impact compressive behavior of warp-knitted spacer fabrics developed for human body protections. A series of warp-knitted spacer fabrics was produced on a double-needle bar Raschel warp knitting machine by varying their structural parameters, including spacer monofilament inclination and fineness, fabric thickness, and surface layer structure. A drop-weight impact tester was used to test these fabrics with predefined impact energy. The impact process of a typical spacer fabric was analyzed based on its impact contact force-displacement curve, energy absorbed-contact force curve and transmitted force-time curve. The effects of the structural parameters on the impact compressive behavior of the warp-knitted spacer fabrics were also discussed. The relationship between the peak transmitted force and peak contact force was established for these fabrics. The study shows that the warp-knitted spacer fabrics can be used as a type of effective material for human body protection d...

Yanping Liu

Papers

A review on auxetic structures and polymeric materials

X-ray diffraction study of bamboo fibers treated with NaOH

Negative Poisson’s Ratio Weft-knitted Fabrics:

Compression behavior of warp-knitted spacer fabrics for cushioning applications

Impact compressive behavior of warp-knitted spacer fabrics for protective applications