The thermodynamic properties of 154 mineral end-members, 13 silicate liquid end-members and 22 aqueous fluid species are presented in a revised and updated data set. The use of a temperature-dependent thermal expansion and bulk modulus, and the use of high-pressure equations of state for solids and fluids, allows calculation of mineral–fluid equilibria to 100 kbar pressure or higher. A pressure-dependent Landau model for order–disorder permits extension of disordering transitions to high pressures, and, in particular, allows the alpha–beta quartz transition to be handled more satisfactorily. Several melt end-members have been included to enable calculation of simple phase equilibria and as a first stage in developing melt mixing models in NCKFMASH. The simple aqueous species density model has been extended to enable speciation calculations and mineral solubility determination involving minerals and aqueous species at high temperatures and pressures. The data set has also been improved by incorporation of many new phase equilibrium constraints, calorimetric studies and new measurements of molar volume, thermal expansion and compressibility. This has led to a significant improvement in the level of agreement with the available experimental phase equilibria, and to greater flexibility in calculation of complex mineral equilibria. It is also shown that there is very good agreement between the data set and the most recent available calorimetric data.

An internally consistent thermodynamic data set for phases of petrological interest

Zircon is the main mineral in the majority of igneous and metamorphic rocks with Zr as an essential structural constituent. It is a host for significant fractions of the whole-rock abundance of U, Th, Hf, and the REE (Sawka 1988, Bea 1996, O’Hara et al. 2001). These elements are important geochemically as process indicators or parent isotopes for age determination. The importance of zircon in crustal evolution studies is underscored by its predominant use in U-Th-Pb geochronology and investigations of the temporal evolution of both the crust and lithospheric mantle. In the past decade an increasing interest in the composition of zircon, trace-elements in particular, has been motivated by the effort to better constrain in situ microprobe-acquired isotopic ages. Electron-beam compositional imaging and isotope-ratio measurement by in situ beam techniques—and the micrometer-scale spatial resolution that is possible—has revealed in many cases that single zircon crystals contain a record of multiple geologic events. Such events can either be zircon-consuming, alteration, or zircon-forming and may be separated in time by millions or billions of years. In many cases, calculated zircon isotopic ages do not coincide with ages of geologic events determined from other minerals or from whole-rock analysis. To interpret the geologic validity and significance of multiple ages, and ages unsupported by independent analysis of other isotopic systems, has been the impetus for most past investigations of zircon composition. Some recent compositional investigations of zircon have not been directly related to geochronology, but to the ability of zircon to influence or record petrogenetic processes in igneous and metamorphic systems.

Sedimentary rocks may also contain a significant fraction of zircon. Although authigenic zircon has been reported (Saxena 1966, Baruah et al. 1995, Hower et al. 1999), it appears to be very rare and may in fact be related to …

/pdf/the-composition-of-zircon-and-igneous-and-metamorphic-1g2xfkpi4l.pdf

The Composition of Zircon and Igneous and Metamorphic Petrogenesis

We present the first finding of continental crust-derived Precambrian zircons in garnet/spinel pyroxenite veins within mantle xenoliths carried by the Neogene Hannuoba basalt in the central zone of the North China Craton (NCC). Petrological and geochemical features indicate that these mantle-derived composite xenoliths were formed by silicic melt^lherzolite interaction. The Precambrian zircon ages can be classified into three age groups of 2·4^2·5 Ga, 1·6^2·2 Ga and 0·6^1·2 Ga, coinciding with major geological events in the NCC. These Precambrian zircons fall in the field of continental granitoid rocks in plots of U/Yb vs Hf and Y. Their igneous-type REE patterns and metamorphic zircon type CL images indicate that they were not crystallized during melt^peridotite interaction and subsequent high-pressure metamorphism.The 2·5 Ga zircons have positive eHf(t) values (2·9^10·6), whereas the younger Precambrian zircons are dominated by negative eHf(t) values, indicating an ancient continental crustal origin.These observations suggest that the Precambrian zircons were xenocrysts that survived melting of recycled continental crustal rocks and were then injected with silicate melt into the host peridotite. In addition to the Precambrian zircons, igneous zircons of 315 3 Ma (2 ), 80^170 Ma and 48^64 Ma were separated from the garnet/spinel pyroxenite veins; these provide evidence for lower continental crust and oceanic crust recycling-induced multi-episodic melt^peridotite interactions in the central zone of the NCC. The combination of the positive eHf(t) values (2·91^24·6) of the 315 Ma zircons with the rare occurrence of 302^324 Ma subduction-related diorite^granite plutons in the northern margin of the NCC implies that the 315 Ma igneous zircons might record melt^peridotite interactions in the lithospheric mantle induced by Palaeo-Asian oceanic crust subduction. Igneous zircons of age 80^170 Ma generally coexist with the Precambrian metamorphic zircons and have lower Ce/Yb and Th/U ratios, higher U/Yb ratios and greater negative Eu anomalies.The eHf(t) values of these zircons vary greatly from ^47·6 to 24·6.The 170^110 Ma zircons are generally characterized by negative eHf(t) values, whereas the 110^100 Ma zircons have positive eHf(t) values.These observations suggest that melt^peridotite interactions at 80^170 Ma were induced by partial melting of recycled continental crust. The 48^64 Ma igneous zircons are characterized by negligible Ce anomalies, unusually high REE, U and Th contents, and positive eHf(t) values.These features imply that the melt^peridotite interactions at 48^64 Ma could be associated with a depleted mantle-derived carbonate melt or fluid.

Continental and Oceanic Crust Recycling-induced Melt^Peridotite Interactions in the Trans-North China Orogen: U^Pb Dating, Hf Isotopes and Trace Elements in Zircons from Mantle Xenoliths

The Central Asian Orogenic Belt ( c . 1000–250 Ma) formed by accretion of island arcs, ophiolites, oceanic islands, seamounts, accretionary wedges, oceanic plateaux and microcontinents in a manner comparable with that of circum-Pacific Mesozoic–Cenozoic accretionary orogens. Palaeomagnetic and palaeofloral data indicate that early accretion (Vendian–Ordovician) took place when Baltica and Siberia were separated by a wide ocean. Island arcs and Precambrian microcontinents accreted to the active margins of the two continents or amalgamated in an oceanic setting (as in Kazakhstan) by roll-back and collision, forming a huge accretionary collage. The Palaeo-Asian Ocean closed in the Permian with formation of the Solonker suture. We evaluate contrasting tectonic models for the evolution of the orogenic belt. Current information provides little support for the main tenets of the one- or three-arc Kipchak model; current data suggest that an archipelago-type (Indonesian) model is more viable. Some diagnostic features of ridge–trench interaction are present in the Central Asian orogen (e.g. granites, adakites, boninites, near-trench magmatism, Alaskan-type mafic–ultramafic complexes, high-temperature metamorphic belts that prograde rapidly from low-grade belts, rhyolitic ash-fall tuffs). They offer a promising perspective for future investigations.

/pdf/tectonic-models-for-accretion-of-the-central-asian-orogenic-4rjcoan76s.pdf

Tectonic models for accretion of the Central Asian Orogenic Belt

Geochemical fingerprinting of oceanic basalts with applications to ophiolite classification and the search for Archean oceanic crust

A series of paleogeographic maps of the Japanese Islands, from their birth at ca 750–700 Ma to the present, is newly compiled from the viewpoint of plate tectonics. This series consists of 20 maps that cover all of the major events in the geotectonic evolution of Japan. These include the birth of Japan at the rifted continental margin of the Yangtze craton (ca 750-700 Ma), the tectonic inversion of the continental margin from passive to active (ca 500 Ma), the Paleozoic accretionary growth incorporating fragments from seamounts and oceanic plateaux (ca 480-250 Ma), the collision between Sino-Korea and Yangtze (250–210 Ma), the Mesozoic to Cenozoic accretionary growth (210 Ma-present) including the formation of the Cretaceous paired metamorphic belts (90 Ma), and the Miocene back-arc opening of the Japan Sea that separated Japan as an island arc (25-15 Ma).

Paleogeographic maps of the Japanese Islands: Plate tectonic synthesis from 750 Ma to the present

High-P/T metamorphic belts were classified into types A and B according to their protoliths. The A-type (collision-type) blueschists possess passive-margin protoliths characterized by platform-type carbonates, bimodal volcanics, and peraluminous sediments. B-type (Cordilleran-type) blueschists consist of active continental-margin protoliths in an accretionary complex characterized by bedded chert, MORB and ocean-island basalts, reef limestones, and graywackes. The spatiotemporal distribution of blueschists and eclogites of the world was compiled; among 250 recognized high-P/T belts, about 20% belong to the A type and the rest to the B type. Most A-type zones lie in Europe and the Tethyan domain, include ultrahigh-pressure metamorphic terranes, and have metamorphic pressure up to 45 kbar. B-type zones occur mainly in the circum-Pacific orogenic belts and intracontinental orogens in Asia, and were recrystallized at P <12 kbar. Associated peridotites include garnet peridotite in the A type and strongly serpe...

Blueschists and Eclogites of the World and Their Exhumation

Paleogeographic reconstruction and origin of the Philippine Sea

https://ea.c.u-tokyo.ac.jp/earth/Members/Isozaki/90AccretedOM.pdf

Shigenori Maruyama

Papers

Paleogeographic maps of the Japanese Islands: Plate tectonic synthesis from 750 Ma to the present

Blueschists and Eclogites of the World and Their Exhumation

Paleogeographic reconstruction and origin of the Philippine Sea

Accreted oceanic materials in Japan

Anatomy of a Cambrian suture in Gondwana: Pacific-type orogeny in southern India?